Thursday, October 31, 2019

Middle-aged and older people observation Essay Example | Topics and Well Written Essays - 1250 words

Middle-aged and older people observation - Essay Example It is well known that no two persons are alike and I have found the same in almost every body but the most significant and identifiable aspect what I found is that the people within a particular age group tend to behave in almost the same manner. This almost similar behavior might be due to similar socio economic background from which they come from. Some of the middle-aged people coming from somewhat rich background tend to behave in a more dignified manner even though they are older than the people who are from a poor background. With this observation what I really came to know is that older people who lead significantly decent life through ought their life have a deeper understanding towards their life and will try to act accordingly in public. On the other way round poor middle aged and older people do not try to behave accordingly in public and according to the situation. On older people there past life influences their present state of behavior a lot. I have observed six people who are all above fifty-eight years. The first person I have observed is an old man who has retired long back from Military Air force. He has receding hairline and is slender built but very active, red in color, very lively person and pretty intelligent, was very communicative, very popular among the people coming to the library. I was observing this person from almost a week and could gather most of the information related to by simply over hearing the discussion between their old friends in the public library. Since he was worki ng in Air force earlier he is quite informative and communicative too. He has three children and all are working but no one is yet married. Being slender built he is very energetic and his actions are not at all like an old man. He even helps his fellow old men in climbing stairs. He is very popular among women coming to the library. He discusses all issues going in his home and even enquires about others

Tuesday, October 29, 2019

Why do constructivists believe that identity matters Do you agree Essay

Why do constructivists believe that identity matters Do you agree Critically evaluate - Essay Example It is with this respect that Constructivism as a theory tries to explain how humans learn and construct their knowledge and understanding of their environment. Checkel (1998) found that knowledge acquisition is a continuous active process whereby learners tend to construct or develop ideas which are normally based on their previous and current knowledge. In order to make decisions, learners depend on cognitive structure to formulate hypothesis and come up with decisions based on the selected information. Klotz and Lynch (2007) described cognitive structure as a mental structure that gives a learner’s experience some organization and meaning. Although learners always come across new experiences, constructivists believe that an individual possesses internal power to give meaning to their new experiences (McGrew, 2011a). McGrew (2011b) further argues that the power resides only within an individual and not within the institution that surrounds them. Alexander Wendt’s theory of constructivism is based on the identity concept of an individual in the process of knowledge acquisition (Checkel, 1998). Identity being the core concept of Constructivism theory, Price and Reus-Smit (1998) defined it as an aspect that uniquely distinguishes an individual from the rest. An aspect that an individual tends to take pride in and which more or less cannot be changed. Checkel (1998) found that identity is influenced by the learner’s background and cultural origin, since people adapt what they come across in the society they are raised in. In this regard, society plays a major role in molding up an individual’s identity because learners build up knowledge based on their perspective of the experiences they encounter. Finnemore (2011) states that it is also necessary to put into account the cultural background of an individual in their process of learning since it helps in shaping out the knowledge that they create. Due to the diversity of cultures, individuals tend to

Sunday, October 27, 2019

Rhenium Oxide (ReO3) and Highly Applied Pressure

Rhenium Oxide (ReO3) and Highly Applied Pressure Describe the symmetry characteristics of the ReO3 polymorphs and their relationship to applied pressure. Rhenium Oxide also known as ReO3 has been researched and looked into detail widely with the use of highly applied pressure. ReO3 is described as a non distorted structure at surrounding pressure levels. Accurate and precise measurements of the pressure-volume relationship crafted by Batloff showed that the transistion pressure was at a value of 5.0kbar and also presented that volume strain is related to (P-PC)2/3. Differences in volume strain was evidently great when comparing with other materials that went through the same process.The reason for this large difference was due to the buckling of the Re-O-Re bonds while ReO6 continued to be firm and strong. With the assumption that octahedral rotation is always as rigid units,stress on rotations that are small will be directly related to the square of the rotation angle, Ø that leads to Ø2. This in turn would allow the polymorph to transform into various phases. The curvature behaviour which was found by Razavi starts at low temp eratures with pressure level of 3kbar.M3 phonons being triply degenerate allows the surrounding temperature of ReO3 with a ambient pressure to have a Pm-3m symmetry. At this current stage it will undergo a transition to a structure that contains a Im-3 symmetry. When changed to a tetragonal form, it will be P4/mbm at 5.2kbar and cubic Im3 at 7.3kbar at increased levels of pressure. The Im3 structures were formed with the process known as condensation from one, two or three M3 phonons. With this transformation, the cubic structure will go through a rhombohedral phase with the symmetry structure of R-3c. The current R-3c will morph again to a rhombohedral phase. ReO6 being a octahedral undergoes a distortion at high pressure, giving a rotation angle of (P-PC) ÃŽ ² where ÃŽ ²=0.322(5) (ÃŽ ² describes the large critical region where the rotation angle is more than 14Â º) that is valid from pressure levels of 5.0 to 27.4kbar. Pressure measurements are mainly done to identify different h igh pressure formations of the ReO3 and the quantity of these formations. Particularly with the use of the time of flight Laue method, when the pressure formation reaches a value of 15 kbar, the structure deduced as a cubic Im3. Despite, the discovery there was a downturn which was the values tabulated was only at a single pressure point. Therefore the entire formation of the breakdown of the structured could not be figured out. Describe the metrical relationships between the polymorph unit cells and ReO6 octahedral tilting. Use the CIF files to create ATOMS drawings that support your analysis. The malformation of perovskite structures can be acquired with reference from the Pm3m structure by rotating the octahedral about the cubic axes. High tension and stress arrangements can be identified and elaborated with the aid of 23 various rotating arrangements that was discovered by Glazer. Respective symmetry groups for high stress transitions include the P4/mbm and Im3 where both groups are homogenous with the M3 phonon condensation. The element Re is fixed in the 8c position in the Im3 space group with only 2 thermal values whereas the oxygen atoms is found to be at the 24g position with 4 thermal values. With a increased in the loading added to the P4/mbm structure will create a deceasing strain that may deform the structure. P4/mbm being a 7 lattice point structure has a normal way of placing the positions of the elements found in ReO3. The Rhenium element is located in the 2b position while the oxygen atom would be fixated in the 4h and 2a position. In the presence of surro unding atmospheric pressure, the direct dependency of the oxygen atoms is fairly lower in the Im3 group than the one found in the Pm3m.In the Im3 unit cell for the ReO3, rotation was done around the coordinates of (111) for the eight sided compound. Evidently P4/mbm produces a nonzero seven sided pull that creates a positive and negative strain value. This rotation created the process of condensation that affected all three M3 phonons. Deformation in the eight sided ReO6 produces two different Re-O bond distances in the P4/mbm formation while there would only be a single Re-O bond found in the Im3 strucutres.Re-O bonds parallel with the c axis will remain in a pressed state when turned whereas Re-O bond that are normal to the c axis will not be in a pressed position but instead arranged in an order where there are gaps.However both formations include double O-O corners of the octahedron that is used to quantify any errors in ReO6.However the O-O distances found in the Im3 and P4/mbm are varied at a pressure value of 27.40kbar that leads to certain abnormalities but can be ignored as trivial. Explain the distortion of the ReO6 octahedra with pressure and quantify the ReO6 octahedral titlting. The deformation and the distortion of the ReO6 octahedron is usually found in the P4/mbm and Im3 structures. Starting with the P4/mbm, there are two symmetry Re-O bonds which are not equal in nature. With the process known as the powder neutron diffraction , the results obtained shows the in depth structural details of the transformation with the function of pressure and thus this confirms that at least 2 high pressure phases are present. When the ReO6 octahedra are rotated they are observed more with ease through the neutrons than the x rays. The method known as Rietveld method of the structural refinement with the high resolution powder data produces the single-crystal neutron diffraction study and this would allow the pressure dependence of the distortion to be measured with sufficient accuracy to state that the order parameter exponent ÃŽ ² where Ø is proportional to the (P-Pc) ÃŽ ² presents the pressure dependence of the rotation angle. This pressure based on the rotation ang le is illustrated well by the law of power in the formula Ø~(P-Pc) ÃŽ ².Ø against the pressure and the curve is plotted with this reference. The result from the exponent ÃŽ ² was obtained with the linear gradient of the slope of the lnØ against the ln(P-Pc) curve that produces the value of ÃŽ ²=0.322(5). Through the discrepancies Ø is always continuing with the stress value of 5 kbar despite the direction of the rotation axis that would vary from (100) to (111) during the change from P4/mbm to the Im3 phase (5.3kbar). With condensation of one, two or three M3 phonons would increase the phase transition from Pm3m to P4/mbm to I4/mm and lastly to the Im3 that have usually been seen in Nax WO3 during the M3 phonon condensation upon cooling. The parameter for the phase transition would be a three component order with the Ø as the magnitude of the rotation angle surrounding the direction of the rotation aixs. The transformation from Pm3m to any of the groups between the P4 /mbm, I4/mmm and Im3 would be the first order that would produce from the rotation around a axis. Abnormalities in the lattice during the transformation would have been seen in the Nax WO3.

Friday, October 25, 2019

Mozart :: essays research papers

A short time before the death of Mozart, a stranger of remarkable appearance, and dressed in deep mourning, called at his house, and requested him to prepare a Requiem, in his best style, for the funeral of a distinguished person. The sensitive imagination of the composer immediately seized upon the circumstance as an omen of his own fate; and the nervous anxiety with which he labored to fulfill the task, had the effect of realizing his impression. He died within a few days of completing this magnificent piece of music, which was performed at his interment. Mozart's unfinished Requiem has long been shrouded in mystery. Mozart undertook the commission for an Austrian nobleman, little knowing that he was to write a requiem for himself. Inevitably, the secrecy surrounding the anonymous commission, the circumstances of Mozart's death, the unfinished state of the work, and its completion under the direction of Mozart's widow, Constanze, have precipitated two centuries of romantic speculation and scholarly controversy.   Ã‚  Ã‚  Ã‚  Ã‚  One book that further explores the history and an analytical study on the Requiem is Christoph Wolff’s Mozart’s Requiem. Christoph Wolff provides a critical introduction to the Requiem in its many facets. Mozart’s Requiem has been a topic discussed for centuries and in Wolff’s book that topic is meticulously broken down. Wolff breaks the book down in two parts. Part I of his study focuses on the tangled genesis and completion of the work and its fascinating early reception history until Constanze's death. Wolff summarizes the current state of research on the subject, provides new perspectives on Mozart's conception of the whole work, and surveys his contributions to the movements composed by his assistant, Sà ¼ssmayr. Part II provides a musical analysis of Mozart's composition, including contextual, structural, and interpretive aspects.

Thursday, October 24, 2019

AP Biology: The Properties of Water Essay

Water has many unique properties that make life possible on Earth. One property is cohesion. The cohesion property is properly defined as the binding of water molecules by hydrogen bonds. Water has this property as a result of the chemical bonding between water. Cohesion of the strong hydrogen bonds allows the water molecules to stick together, almost as a unit of one. A force exerted on one of the molecules will be exerted on all of the adjacent molecules as a result of cohesion. Cohesion, often with the cooperation of adhesion, the clinging of one substance to another, adds to the function and ability of water to overcome strong natural forces, such as gravity. When water is in its liquid state of matter, the hydrogen bonds are very frail and weak, about one-twentieth as strong as covalent bonds. The bonds are made, broken, and remade very quickly. Each hydrogen bond lasts only a few trillionths of a second, but the constant synthesis of new bonds with a succession of partners acquires equilibrium. Therefore, a significant percentage of all the water molecules are bonded to their neighbors, making water a more orderly structured liquid than most other known liquids. A property related to cohesion is surface tension, a measure of how difficult it is to stretch or break the surface of a liquid. Water is known to have a greater surface tension than most other liquids. An ordered arrangement of hydrogen-bonded water molecules is present at the boundary between water and air. As a result water behaves as though it is coated with an invisible film along the surface. An example how the cohesion of water affects the functioning of living organisms is present in plants. Evaporation from the leaves in plants pulls water up from the roots. Cohesion due to hydrogen bonding helps hold the column of water molecules together within the xylem vessels located in the stem or trunk of a plant. Adhesion helps the process by resisting the pull of gravity against the upward motion of the molecules. Another property of water is its solubility. Water is known as the universal solvent of life. Many substances can be combined with water to form a solution, a homogeneous mixture between two substances. Water, in solutions, is known as the solvent. The substance or substances being dissolved is known as the solute. An aqueous solution is when a homogenous mixture where water is the solvent is present. As found by the medieval alchemists, water is the most soluble liquid. Although water is technically not universal, it  is very versatile solvent. Water’s solubility is a result of its polarity. Water is a polar molecule, meaning that the opposite ends of the molecule of opposite charges. In a water molecule, the polar covalent bonds allow the oxygen region of the molecule to have a partial negative charge and the hydrogen regions to have a partial positive charge. When ionic crystals are placed in water, they are ionized. The partially negative ion from the crystal bond to the hydrogen ions in water. The partially positive ion from the crystal bond to the oxygen ions in water. The sphere of water molecules around each dissolved ion is called a hydration shell. Water eventually dissolves all the ions. As a result, there is a solution containing two solutes from the salt homogeneously mixed with water, the versatile solvent. Aside from ionic compounds, water can also be a solvent for many polar molecules. An effect of the versatile solubility can be demonstrated in the functioning of many liquid substances of living organisms, such as blood, the sap of plants, and the liquid contained in cells. Water’s solubility allows for these liquids to have a universal concentration throughout the entire liquid, making the distribution of the ions or molecules in the solution equal. Another property of water is its high specific heat. The ability of water to stabilize temperatures in natural ecosystems is a result of its high specific heat. Specific heat is defined as the amount of heat that must be absorbed or lost for one gram of a substance to change its temperature by one degree Celsius. Water’s specific heat is defined as one calorie per gram per degree Celsius. This information comes from the definition of a calorie, the amount of heat that causes one gram of water to change its temperature by one degree Celsius. Because of water’s high specific heat, water’s temperature will change less when it absorbs or loses a certain amount of heat. Water resists changing its temperature, and when it happens to change it, it absorbs or loses a large quantity of heat for each change in temperature. Water’s specific heat is a direct result of hydrogen bonding. Large amounts of heat must be absorbed in order to break the hydrogen bonds, and la rge amounts of heat are released when hydrogen bonds form. One calorie doesn’t cause a large change in the temperature primarily because most of the heat energy is used to disrupt the hydrogen bonds before the water  molecules can start moving faster. When the temperature drops slightly, many hydrogen bonds form, releasing a large amount of heat energy. Water’s high specific heat is directly related to life on Earth through climate. Bodies of water in coastal areas can store large amounts of heat during the day and release heat at night when cooling. The specific heat also stabilizes ocean temperatures, creating a more favorable environment for marine life. Therefore, as a result of water’s high specific heat, the water on Earth keeps temperature changes on land and in water within life-permitting limits. Animals are also mostly made of water, allowing them to resist changes in their own temperatures. Water is so abundant and present in everyday life that it’s easy to neglect the fact that it is an exceptional s ubstance with many extraordinary qualities. Following the theme of emergent properties, water’s unique behavior can be traced to the structure and interactions of its molecules.

Wednesday, October 23, 2019

Death of a family member Essay

In this chapter on Crisis in Family, the death of one’s child, parent, or suicide of a close family member can cause a devastating crisis within a marriage. Mothers and fathers relate to death in different ways, which causes conflict within the marriage. Depending on the circumstances of the death, one spouse may accuse the other of not sharing in the grief, or blaming the other for the death of the child. In dealing with your partner patience should be implemented, thus allowing the other person to grieve in their own way. Most people expect that they will eventually lose a parent, however the death of a child is not foreseen. Death of a parent can cause crisis before the parent passes if they have been terminally ill. By the time the parent dies the emotional strain, and stress from the illness may have been so draining that the crisis has already occurred. The loss of a parent can cause one to feel anger, depression, and lack of concentration. A study done on college students found that their constant reminiscing about the death of a parent or close loved one caused them to have a lower sense of psychological well-being. Whether it is the death of a parent or child, grief is not a one-time experience that people go through and move on. For some it is a chronic sorrow where grief related feelings occur periodically throughout the rest of their lives. When you think of the way things may have been if a loved one was still here, along with on the anniversary of their passing feelings of grief become more severe. A study done by Burke in 1999 showed that after 2 to 20 years 97 percent of people who lost a loved one still showed signs of chronic sorrow. In dealing with suicide of a family member, annually there are 31,000 suicides and (75,000) attempts. Each suicide is said to immediately affect 6 other people in the person’s life. These affects range from physical disorders like shingles (due to stress), depression (grief), and social stigma (the  person is viewed as weak and the family as a failure in not being able to help the prior emotions and feelings of the family member). It has further been stated that family members that witnessed the suicide of a family member described this as the worst day of their lives. The people who are most vulnerable to suicide are: 15 to 19 years old, homosexual, or male, family history of suicide or mood disorder, substance abuse or past history of child abuse and parental sex abuse. Therapist view suicide as a permanent solution to a temporary problem. Family members often think they could have done something to prevent the suicide. However Therapist have stated that if a person wants to end their life they will and you can’t control it. Support groups can be an effective coping mechanisms, realizing that you can’t stop a person who is adamant about taking his or her own life. This section of the chapter dealing with death of a family member holds near and dear to my heart. Due to the recent passing of my dad, I was able to relate to so many of the emotions expressed in this chapter. After being diagnosed with Chronic Heart disease and extensive open heart surgery, I watched my dad’s downward spiral for 7 months. I witnessed the hope that my mom had even when the doctors displayed hopelessness. It was difficult for me witnessing my dad’s decline on a daily bases, however for my siblings it was equally as difficult, because they wanted to be here but were not able to due to their own family and job obligations in other states. In addition to the experiences that have been recorded in this chapter, I would like to add a few personal experiences that we endured. My dad was the eldest of 12, and we were a close knit family. However during my dad’s illness, his desire to see his siblings and other members of the family decreased. This brought about feelings of anger for them, and much of it directed against our immediate family. I noticed that sometimes family are more concerned about their feelings than those that are suffering from the illness. Even though my dad has been gone for nearly a year it still seems very current. There is not a day that passes that I don’t think of him in some capacity. I have moments of sorrow, I have also felt moments of despair when someone else talks about their dad. There were time in church where I would just begin to cry because the song reminded me of him. I also am reminded every Sunday of the chair that he occupied when he was there. My mom and I have struggled with parting with my dad’s belongings. She has several vehicles, and does  not need them all, however we want to keep them, because they belonged to my dad even though it is not the practical thing to do. We have done quite a few things to help cope with the loss of my dad. We have had a memorial service on father’s day where we had a butterfly release ceremony. Now every time we see a butterfly it reminds us that he is not far. I also have a picture of him by my bed, on my dresser and on the refrigerator. Just these small reminders help us to cope with my dad no longer being with us on this time side of life. My mom stays really busy, with bowling, working, and church activities. She said that staying busy keeps her mind off of my dad not being with her. It has been a great adjustment, because after 52 years of marriage and sharing everything that you do, the single life, not by choice is a stressor all by itself. Whenever I feel weary about my dad’s passing, I think of those last days and how his body had suffered so much from his illness. I would never want to be so selfish as to want him to stay here and not have the quality of life that he deserved to have. I believe that our greatest coping mechanism is the assurance that we will meet my dad in another place, not on this time side of life.